Theory of square-wave voltammetry of two-step electrode reaction with kinetically stabilized intermediate (CROSBI ID 173468)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj
engleski
Theory of square-wave voltammetry of two-step electrode reaction with kinetically stabilized intermediate
Square-wave voltammograms of quasireversible EE mechanism with thermodynamically unstable intermediate may consist either of a single peak, or of two peaks if the second electron transfer appears quasireversible at the lowest frequency and irreversible at the highest frequency. The development of the second peak depends on the critical dimensionless kinetic parameter which was calculated in this paper. This parameter can be used for the estimation of standard rate constant of the second electrode reaction.
two-step electrode reaction ; EE mechanism ; kinetics of electrode reaction ; square-wave voltammetry
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Podaci o izdanju
660 (1)
2011.
22-25
objavljeno
1572-6657
1873-2569
10.1016/j.jelechem.2011.05.026