Photochemical production of LiCd from Cd and Li2 F 1Sigmag+ state (CROSBI ID 79978)
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Azinović, Davorka ; Milošević, Slobodan ; Pichler, Goran
engleski
Photochemical production of LiCd from Cd and Li2 F 1Sigmag+ state
Blue-green excimer band of $Čš7ć$LiCd was observed as a result of $Čš7ć$Li$% _š2ć$(F $Čš1ćSigma _šgćČš+ć$)+Cd$ ightarrow Čš7ć$LiCd (2 $Čš2ćPi $)+Li photochemical reaction. Lithium dimer was excited into F $Čš1ćSigma _šgćČš+ć $ by using optical-optical double resonance excitation with single dye laser photons in the 615-671 nm range where a number of accidental resonances (X$% Čš1ćSigma _šgćČš+ć ightarrow $A$Čš1ćSigma _šućČš+ć ightarrow $F$% Čš1ćSigma _šgćČš+ć$) occur. The reactivity of the excited gerade state in the formation process of the intermetallic excimers is comparable to reactivity of the ungerade states.
photochemical reactions; intermetallic excimers
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