The LiHg(2 2Pi3/2 - X 2Sigma 1/2+) System (CROSBI ID 79983)
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Podaci o odgovornosti
Gruber, Dieter ; Li, X. ; Windholz, L. ; Gleichmann, M.M. ; Hess, B.A. ; Vezmar, I. ; Pichler, Goran
engleski
The LiHg(2 2Pi3/2 - X 2Sigma 1/2+) System
We report the determination of the complete LiHg shallow bound ground state potential curve by combination of laser-induced fluorescence spectroscopy of bound-bound transitions, photoassociation spectroscopy of bound-free transitions, and ab initio calculations. The results are evaluated by comparison of quantum mechanically simulated emission spectra with experimental data and used to describe spectroscopic features of the 223/2- band as well as the photochemical formation via excitation of the lithium dimer.
lithium dimer; LiHg; laser induced fluorescence
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