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Kinetic study of free radical copolymerization of dodecyl methacrylate and styrene using diperoxide initiator (CROSBI ID 41589)

Prilog u knjizi | izvorni znanstveni rad

Šoljić, Ivana ; Penović, Tomislav ; Jukić, Ante ; Janović, Zvonimir Kinetic study of free radical copolymerization of dodecyl methacrylate and styrene using diperoxide initiator // AIDIC Conference Series Vol. 9, Selected papers from 9th International Conference on Chemical and Process Engineering 2009 / Sauro Pierucci (ur.). Rim: Italian Association of Chemical Engineering (AIDIC), 2009. str. 283-292

Podaci o odgovornosti

Šoljić, Ivana ; Penović, Tomislav ; Jukić, Ante ; Janović, Zvonimir

engleski

Kinetic study of free radical copolymerization of dodecyl methacrylate and styrene using diperoxide initiator

In this study kinetics of the free radical copolymerization of styrene and dodecyl methacrylate in xylene solution using diperoxide initiator, up to high conversions, was investigated. Kinetic results and structural properties of the synthesized polymers were compared with values obtained for homopolymerization and copolymerization systems initiated with conventional monofunctional initiator. It was established that higher polymerization rates could be achieved by using diperoxide initiator while maintaining high values of molecular weight and a relatively narrow polydispersity index. However, in copolymerization systems with higher mole fractions of dodecyl methacrylate in initial feed, the fall of diperoxide initiator efficiency was observed.

free radical copolymerization, kinetics, structural properties, diperoxide initiator, styrene, dodecyl methacrylate

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Podaci o prilogu

283-292.

objavljeno

Podaci o knjizi

AIDIC Conference Series Vol. 9, Selected papers from 9th International Conference on Chemical and Process Engineering 2009

Sauro Pierucci

Rim: Italian Association of Chemical Engineering (AIDIC)

2009.

978-88-95608-10-5

Povezanost rada

Kemijsko inženjerstvo