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Vapor–Liquid Equilibria in the Polystyreneplus-Toluene System at Higher Solvent Concentrations (CROSBI ID 215155)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Pavliček, Jan ; Bogdanić, Grozdana ; Wichterle, Ivan Vapor–Liquid Equilibria in the Polystyreneplus-Toluene System at Higher Solvent Concentrations // Chemical and biochemical engineering quarterly, 29 (2015), 1; 1-4

Podaci o odgovornosti

Pavliček, Jan ; Bogdanić, Grozdana ; Wichterle, Ivan

engleski

Vapor–Liquid Equilibria in the Polystyreneplus-Toluene System at Higher Solvent Concentrations

Vapor–liquid equilibria (VLE) were determined in the polystyrene + toluene system under isothermal conditions using an improved all-glass microebulliometer with circulation of the liquid phase for the dynamic measurement of the total pressure over liquid mixtures. The experimental data were correlated using the universal quasichemical (UNIQUAC) free-volume (FV) model, and the applicability of three known predictive models was tested. It was found that the VLE predictions made using the group contribution-Flory equation of state, the UNIFAC-vdW-FV, and the entropic- FV model are of the same quality.

Correlation; Ebulliometer; Experimental data; Polymer–solvent system;

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Podaci o izdanju

29 (1)

2015.

1-4

objavljeno

0352-9568

Povezanost rada

Kemija, Kemijsko inženjerstvo, Temeljne tehničke znanosti

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