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Effect of acidity and texture of micro-, mesoporous, and hybrid micromesoporous materials on the synthesis of paramenthanic diol exhibiting anti-Parkinson activity (CROSBI ID 232348)

Prilog u časopisu | izvorni znanstveni rad

A. Torozova, P. Mäki-Arvela, N. D. Shcherban, N. Kumar, A. Aho, M. Stekrova, K. Maduna Valkaj, P. Sinitsyna, S. M. Filonenko, P. S. Yaremov, V. G. Ilyin, K. P. Volcho, N. F. Salakhutdinov, D. Yu. Murzin Effect of acidity and texture of micro-, mesoporous, and hybrid micromesoporous materials on the synthesis of paramenthanic diol exhibiting anti-Parkinson activity // Catalysis, structure & reactivity, 1 (2015), 146-154. doi: 10.1179/2055075815Y.0000000009

Podaci o odgovornosti

A. Torozova, P. Mäki-Arvela, N. D. Shcherban, N. Kumar, A. Aho, M. Stekrova, K. Maduna Valkaj, P. Sinitsyna, S. M. Filonenko, P. S. Yaremov, V. G. Ilyin, K. P. Volcho, N. F. Salakhutdinov, D. Yu. Murzin

engleski

Effect of acidity and texture of micro-, mesoporous, and hybrid micromesoporous materials on the synthesis of paramenthanic diol exhibiting anti-Parkinson activity

Microporous, mesoporous, and new hybrid materials were studied in verbenol oxide isomerization for the synthesis of biologically active substance with anti- Parkinson activity. H-Si-MCM-41, H-Al- MCM-41, H- Al- MCM-48, H-Beta-25, and H-Beta-300 were compared with hybrid materials. The latter with a zeolite-like micromesoporous structure were characterized and evaluated for their catalytic activity for the first time. The approach of dual templating for synthesis of new materials was applied in this work to combine properties of Beta-zeolites and mesoporous cellular foams (MCF). The selectivity to the target product was the highest over microporous mild acidic H-Beta- 300 and hybrid ZF-100, with also mild acidity and even absence of strong acid sites. Selectivity at 97 and 99% of conversion was 61 and 59% for H-Beta-300 and hybrid ZF-100, respectively.

Zeolites ; Hybrid micro-mesoporous materials ; MCM-41 ; MCM-48 ; Beta zeolites ; Verbenol oxide isomerization

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Podaci o izdanju

1

2015.

146-154

objavljeno

2055-0758

10.1179/2055075815Y.0000000009

Povezanost rada

Interdisciplinarne tehničke znanosti, Kemijsko inženjerstvo

Poveznice